Página Inicial CNEA Laboratorio TANDAR Página Inicial TANDAR Historia del acelerador TANDAR Web interno Web mail
Inicio » Actividades I+D > Publicaciones 2003 > [2,6-Bis(1H-benzimidazol-2-yl-κN3)pyridi...
artículo con referato
"[2,6-Bis(1H-benzimidazol-2-yl-κN3)pyridine-κN](dimethylformamide-κO)(thiosulfato-κ2O,S)nickel(II) monohydrate"
E. Freire, S. Baggio, J.C. Muñoz and R. Baggio
Acta Cryst. C 59(8) (2003) m299-m301
The structure of the title compound, [Ni(ths)(bbip)(dmf)]·H2O [ths is thiosulfate, S2O3; bbip is 2,6-bis(1H-benzimidazol-2-yl)pyridine, C21H13N5; and dmf is dimethylformamide, C3H7NO], is monomeric, with the nickel ion octahedrally surrounded by an N,N′,N″-tridentate bbip molecule, an S,O-bidentate ths molecule and an O-monodentate dmf molecule. The H atoms of the hydration water molecule and the amino groups of bbip are involved in hydrogen bonding and determine a spatial organization of broad layers parallel to (001), which are connected by weak interactions.
Av. Gral Paz y Constituyentes, San Martín, Pcia. de Buenos Aires, Argentina
Tel: (54-11) 6772-7007 - Fax: (54-11) 6772-7121