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Inicio » Actividades I+D > Publicaciones 2004 > Tetraaqua(3,4,7,8-tetramethyl-1,10-phena...
artículo con referato
"Tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-κ2N,N′)zinc(II) thiosulfate"
M.E. Díaz de Vivar, S. Baggio, A. Ibañez and R. Baggio
Acta Cryst. C 60(9) (2004) m451-m453
In the title complex of zinc(II) with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmph), viz. [Zn(C16H16N2)(H2O)4](S2O3), the metal atom has a monomeric octahedral ZnN2O4 complex environment comprising two N-atom donors from the tmph group and four aqua O-atom donors. The complex cation is connected to four thiosulfate anions through a compact hydrogen-bonding network involving all coordinated aqua H-atom donors and all the outer acceptors (O and S) of the anion.
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