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artículo con referato
"A new binding mode for thiosulfate in six-coordinate poly[[(1,10-phenanthroline-κ2N,N′)cadmium(II)]-μ-thiosulfato]"
M.E. Díaz de Vivar, S. Baggio and R. Baggio
Acta Cryst. C 60(10) (2004) m495-m497
In the novel title six-coordinate cadmium complex, [Cd(S2O3)(C12H8N2)]n, the anion binds to three different six-coordinate cationic centres through all four external atoms, an unprecedented coordination mode for thiosulfate metal-organic complexes. This connectivity leads to strongly linked dimers, connected to form interleaved double chains, which in turn interact through remarkably short ππ bonds between their phenanthroline groups.
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