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Inicio » Actividades I+D > Publicaciones 2004 > Diaqua(sulfato-κO)[2,4,6-tris(2-pyridyl)...
artículo con referato
"Diaqua(sulfato-κO)[2,4,6-tris(2-pyridyl)-1,3,5-triazine-κ3N1,N2,N6]zinc(II) dihydrate"
M. Harvey, S. Baggio and R. Baggio
Acta Cryst. C 60(10) (2004) m498-m500
In the title compound, [Zn(SO4)(C18H12N6)(H2O)2]·2H2O, the metal complex is monomeric, with an octahedral ZnII centre coordinated by the tridentate ligand 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tpt), two aqua molecules and a monodentate sulfate ion. A complex hydrogen-bonding scheme is built up out of the profuse availability of donors and acceptors (O–HO/N and C–HO) which, in addition to ππ interactions between tpt groups, define a three-dimensional assembly.
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