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artículo con referato
"A novel five-coordinate cadmium phenanthroline thiosulfate"
M. Harvey, S. Baggio, H. Pardo and R. Baggio
Acta Cryst. C 60(2) (2004) m79-m81
The structure of the novel cadmium phenanthroline thiosulfate poly[[(1,10-phenanthroline-κ2N,N′)cadmium(II)]-μ3-thiosulfato-κ3S:S:O], [Cd(S2O3)(C12H8N2)]n, with a pentacoordinated Cd centre, is reported. It forms linear chains built up around a 21 axis and is isostructural with the known bipyridine homologue. The structure is also compared with a previously reported closely related monoaqua monohydrated phase, where the Cd2+ cation is hexacoordinated. The incidence of weak C–HO interactions in the determination of its general packing properties is discussed.
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