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Inicio » Actividades I+D > Publicaciones 2005 > Bis[(acetato-κ2O,O′)bis(4,4′-dimethyl-2,...
artículo con referato
"Bis[(acetato-κ2O,O′)bis(4,4′-dimethyl-2,2′-bipyridyl-κ2N,N′)zinc(II)] trithionate pentahydrate"
M.E. Díaz de Vivar, S. Baggio, M.T. Garland and R. Baggio
Acta Cryst. C 61(6) (2005) m289-m291
The title ionic zinc-acetate complex, [Zn(C2H3O2)(C12H12N2)2]2(S3O6)·5H2O, contains a ZnN4O2 nucleus provided by the three bidentate ligands acting in a chelating mode. The trithionate unit, in turn, acts as an isolated charge-balancing counter-ion. The structure has a three-dimensional assembly achieved through three different interaction types, viz. Coulomb, hydrogen bonding and ππ. The trithionate group and one of the solvent water molecules are disordered around inversion centers.
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