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Inicio » Actividades I+D > Publicaciones 2005 > Pyrazolone-based nitrido complexes: synt...
artículo con referato
"Pyrazolone-based nitrido complexes: synthesis and nitrogen transfer to alkenes"
F.R. Pérez, J. Belmar, Y. Moreno, R.F. Baggio and O. Peña
New J. Chem. 29(1) (2005) 283-287
The first examples of alkylpyrazolone based nitridomanganese(V) complexes are here reported. Styrene was used as a test substrate to study the complex.s ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-2-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.
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