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capítulo de libro
"Dense Fluids: Other Developments - Transport in Supercooled Liquids"
Horacio R. Corti, M. Paula Longinotti, Josefa Fernández, Enriqueta R. López and Alois Würger
Capítulo 9 del libro "Experimental Thermodynamics Volume IX: Advances in Transport Properties of Fluids", Eds. M.J. Assael, A.R.H. Goodwin, V. Vesovic and W.A. Wakeham, Royal Society of Chemistry, London (2014), 391 pp
ISBN: 978-1-84973-677-0 (hardcover)
978-1-78262-149-2 (eBook)
978-1-78262-525-4 (on-line)
Abstract
This chapter reviews recent advances in modelling and predicting some transport properties of dense fluids. We summarize the recent developments for transport in supercooled liquids, focussing on links between structural relaxation and viscosity and decoupling between viscosity and diffusion/mobility. Building on theoretical advances in the supercooled state, we illustrate how density-temperature scaling can be used to correlate and predict viscosity and diffusion coefficients of dense fluids. We complete the chapter by reviewing recent advances in thermal diffusion.
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