Ciclo de Seminarios 2017
2017 10 MAY
Miércoles 10 de Mayo
11:15 hs. - Auditorio Emma Pérez Ferreira
Edificio TANDAR
"Interpretation of Kinetic Processes Governing the Operation of Perovskite Solar Cells"
Dr. Juan Bisquert
(*)
Institute of Advanced Materials, Universitat Jaume I, Castelló, Spain
RESUMEN:
The development of organic-inorganic lead halide perovskites with very large efficiency requires us
to understand the operation of the solar cell. We have used the measurement of impedance
spectroscopy in combination withcurrent-voltage scans and physical modeling to obtain insights
about the physical processes dominating the photovoltaic operation. This class of semiconductors
presents remarkable bulk electronic and optical properties, but the contacts to the device are a
key aspect of the operation and show important dynamic interactions. We provide an interpretation
of capacitances as a function of frequency both in dark and under light, and we discuss the meaning
of resistances and how they are primarily related to the operation of contacts in many cases. The
capacitance reveals a very large charge accumulation at the electron contact, which has a great
impact in the cell measurements, both in photovoltage decays, recombination, and hysteresis.We
present the surface polarization model that gives insight and quantitative description of
current-voltage dynamic hysteresis and impedance spectroscopy loops. We develop a global view of
the formation of photovoltage and the kinetic processes governing the operation of the solar cell,
providing a suitable unified explanation to the many strange observations reported in the last few
years
* Juan Bisquert
<bisquert@uji.es> es Doctor en Física de la Universidad de Valencia, España. Actualmente es el Director del Instituto de Materiales Avanzados de la Universitat Jaume I de Castelló (UJI) donde se desarrolla investigación en materiales, nanoestructuras y dispositivos para la producción y uso eficiente de las energías limpias. Ha publicado 320 trabajos en revistas de investigación, tiene 14000 citas y un factor h de 75. Es Editor Senior en Journal of Physical Chemistry Letters y miembro del comité editorial de Energy and Environmental Science, ChemElectroChem y South Korean Journal of Electrochemical Science and Technology. Bisquert ha sido distinguido por el ISI Highly Cited Researchers (2014, 2015 y 2016). Coopera con la administración de proyecto de investigación en conjunto de la King Abdulaziz University y King Saud University of Saudi Arabia. Su trabajo de investigación se centra en celdas solares de perovskitas, celdas solares nanoestructuradas (incluyendo celdas de Gratzel), water splitting con luz visible, producción de combustibles solares y baterías de litio.